Length scale of dynamic heterogeneity in supercooled glycerol near T-g

TitleLength scale of dynamic heterogeneity in supercooled glycerol near T-g
Publication TypeJournal Article
Year of Publication2001
AuthorsReinsberg, S. A., X. H. Qiu, M. Wilhelm, H. W. Spiess, and M. D. Ediger
JournalJournal of Chemical PhysicsJournal of Chemical Physics
Volume114
Pagination7299-7302
Date PublishedMay
Type of ArticleArticle
ISBN Number0021-9606
Accession NumberWOS:000168168100001
KeywordsDIFFUSION, GLASS-TRANSITION, LIQUIDS, MULTIDIMENSIONAL NMR, NUCLEAR-MAGNETIC-RESONANCE, RATE MEMORY, SPECTROSCOPY, STRUCTURAL RELAXATION
Abstract

This letter presents the first direct measurement of the length scale of dynamic heterogeneity in a low molecular weight glass former without the perturbing effect of probe molecules or confinement. Using a multidimensional C-13 solid-state exchange NMR experiment, 1 nm heterogeneities were found in glycerol for temperatures ranging from 199 K to 207 K (T-g = 189 K). This small size and weak temperature dependence allow some distinctions to be made among different models of the glass transition. It is shown that the dynamics are not influenced by a low concentration (0.1 wt. %) relaxation agent Cu(NO3)(2). (C) 2001 American Institute of Physics.

Alternate JournalJ. Chem. Phys.