Title | Length scale of dynamic heterogeneity in supercooled D-sorbitol: Comparison to model predictions |
Publication Type | Journal Article |
Year of Publication | 2003 |
Authors | Qiu, X. H., and M. D. Ediger |
Journal | Journal of Physical Chemistry BJ. Phys. Chem. B |
Volume | 107 |
Pagination | 459-464 |
Date Published | Jan |
Type of Article | Article |
ISBN Number | 1520-6106 |
Accession Number | WOS:000180410600008 |
Keywords | DIELECTRIC-RELAXATION, ELECTRIC-FIELD, GLASS-FORMING LIQUIDS, MOLECULAR MOBILITY, O-TERPHENYL, STRUCTURAL RELAXATION, T-G, TRANSITION, translational diffusion, VOLUME TEMPERATURE RELATIONS |
Abstract | A direct measurement of the length scale of dynamic heterogeneity in supercooled D-sorbitol has been performed using a multidimensional C-13 solid-state NMR experiment. Several models predict that the growth of this length scale is linked to the slowing of dynamics as the glass transition is approached from above. At 275 K (T-g + 7 K), 2.5 +/- 1.2 nm heterogeneities are detected in sorbitol. This result and recent results of similar measurements on glycerol, o-terphenyl, and poly(vinyl acetate) are compared to various models. The only model in quantitative agreement with these experimental data is based upon local fluctuations in the configurational entropy. |
Alternate Journal | J. Phys. Chem. B |