Length scale of dynamic heterogeneity in supercooled D-sorbitol: Comparison to model predictions

TitleLength scale of dynamic heterogeneity in supercooled D-sorbitol: Comparison to model predictions
Publication TypeJournal Article
Year of Publication2003
AuthorsQiu, X. H., and M. D. Ediger
JournalJournal of Physical Chemistry BJ. Phys. Chem. B
Volume107
Pagination459-464
Date PublishedJan
Type of ArticleArticle
ISBN Number1520-6106
Accession NumberWOS:000180410600008
KeywordsDIELECTRIC-RELAXATION, ELECTRIC-FIELD, GLASS-FORMING LIQUIDS, MOLECULAR MOBILITY, O-TERPHENYL, STRUCTURAL RELAXATION, T-G, TRANSITION, translational diffusion, VOLUME TEMPERATURE RELATIONS
Abstract

A direct measurement of the length scale of dynamic heterogeneity in supercooled D-sorbitol has been performed using a multidimensional C-13 solid-state NMR experiment. Several models predict that the growth of this length scale is linked to the slowing of dynamics as the glass transition is approached from above. At 275 K (T-g + 7 K), 2.5 +/- 1.2 nm heterogeneities are detected in sorbitol. This result and recent results of similar measurements on glycerol, o-terphenyl, and poly(vinyl acetate) are compared to various models. The only model in quantitative agreement with these experimental data is based upon local fluctuations in the configurational entropy.

Alternate JournalJ. Phys. Chem. B