COOPERATIVE MOTION IN FRAGILE LIQUIDS NEAR THE GLASS-TRANSITION - PROBE REORIENTATION IN O-TERPHENYL AND POLYSTYRENE

TitleCOOPERATIVE MOTION IN FRAGILE LIQUIDS NEAR THE GLASS-TRANSITION - PROBE REORIENTATION IN O-TERPHENYL AND POLYSTYRENE
Publication TypeJournal Article
Year of Publication1994
AuthorsBlackburn, F. R., M. T. Cicerone, G. Hietpas, P. A. Wagner, and M. D. Ediger
JournalJournal of Non-Crystalline SolidsJournal of Non-Crystalline SolidsJournal of Non-Crystalline Solids
Volume172
Pagination256-264
Date PublishedSep
Type of ArticleArticle; Proceedings Paper
ISBN Number0022-3093
Accession NumberWOS:A1994PJ19600036
KeywordsANTHRACENE, DEPENDENCE, FORMING LIQUIDS, MOLECULAR-DYNAMICS, ORTHOTERPHENYL, RELAXATION, ROTATIONAL DIFFUSION, SIZE, VISCOUS-LIQUIDS
Abstract

Reorientational relaxation measurements of dilute rigid probes in o-terphenyl and polystyrene are reported. In each matrix, the results span more than 13 decades in time and extend to below the conventional glass transition temperature. The temperature dependence of the observed rotation times is roughly proportional to viscosity divided by temperature, as predicted by the Debye-Stokes-Einstein equation. Consistent with previous work on o-terphenyl [F. Fujara, B. Geil, H. Sillescu and G. Fleischer, Z. Phys. B88 (1992) 195], it is observed that probe rotational motion has a stronger temperature dependence than probe translational diffusion at low temperatures. Using translational diffusion results from the literature, it is shown for the first time that this is also true in a polymeric glass former. These results are inconsistent with several proposed models of cooperativity near the glass transition.

Short TitleJ. Non-Cryst. SolidsJ. Non-Cryst. Solids
Alternate JournalJ. Non-Cryst. Solids